Two-step electron beam excitation of Al2O3 : Cr by gallium nitride recombination radiation

摘要

We report on a two-step excitation process of a GaN/Al2O3:Cr specimen by an external electron beam of 30 keV. The epitaxial growth of GaN on the (0001) faces of ruby is described, as well as the experimental technique applied in the excitation and recording of the combined luminescence spectrum. It is known that the spinel and ruby are frequently used as substrate materials for the epitaxial deposition of GaN. At die same time is ruby one of the most useful layer materials with a red emission line lambda = 694 nm. Due to its dielectric character, the pumping of ruby is performed usually subjecting it to the light of an intense flash lamp. Electron beam excitation, on the other hand, which could be more powerful, is impaired with electrical insulator material. This discrepancy can be removed by a two-step excitation, were at first the semiconducting GaN-layer, epitaxially grown on a (0001)Al2O3:Cr (ruby) crystal is excited to radiation emission by an external electron beam. The following internal absorption process, by the ruby crystal, of the GaN luminescence radiation provides for the characteristic E-2 to (4)A(2)-transition at 1.786 eV. We found a strong and sharp emission line of that photon energy, which additionally displays polarization, typical for the anisotropic uniaxial ruby crystal. Such an indirect electron-beam excitation of ruby allows to generate almost monochromatic red light, and might point into a direction of interesting practical applications. [References: 5]