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Observations of Interstellar Formamide: Availability of a Prebiotic Precursor in the Galactic Habitable Zone

机译:星际甲酰胺的观察:在银河宜居区的益生元前体的可用性。

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摘要

We conducted a study on interstellar formamide, NH_2CHO, toward star-forming regions of dense molecular clouds, using the telescopes of the Arizona Radio Observatory (ARO). The Kitt Peak 12 m antenna and the Submillimeter Telescope (SMT) were used to measure multiple rotational transitions of this molecule between 100 and 250GHz. Four new sources of formamide were found [W51M, Ml7 SW, G34.3, and DR21(OH)], and complementary data were obtained toward Orion-KL, W3(OH), and NGC 7538. From these observations, column densities for formamide were determined to be in the range of 1.1×l0~(12) to 9.1×10~(13) cm~(-2), with rotational temperatures of 70-177 K. The molecule is thus present in warm gas, with abundances relative to H_2 of 1 × 10 ~(-11) to 1×10~(-10). It appears to be a common constituent of star-forming regions that foster planetary systems within the galactic habitable zone, with abundances comparable to that found in comet Hale-Bopp. Formamide's presence in comets and molecular clouds suggests that the compound could have been brought to Earth by exogenous delivery, perhaps with an infall flux as high as ~ 0.1 mol/km~2/yr or 0.18 mmol/m~2 in a single impact. Formamide has recently been proposed as a single-carbon, prebiotic source of nucleobases and nucleic acids. This study suggests that a sufficient amount of NH_2CHO could have been available for such chemistry.
机译:我们使用亚利桑那射电天文台(ARO)的望远镜,对密集分子云的恒星形成区域进行了星际甲酰胺NH_2CHO的研究。 Kitt Peak 12 m天线和亚毫米望远镜(SMT)用于测量此分子在100至250GHz之间的多次旋转跃迁。发现了四个新的甲酰胺来源[W51M,M17 SW,G34.3和DR21(OH)],并获得了有关Orion-KL,W3(OH)和NGC 7538的补充数据。测得甲酰胺的范围为1.1×10〜(12)至9.1×10〜(13)cm〜(-2),旋转温度为70-177 K.相对于H_2的丰度为1×10〜(-11)至1×10〜(-10)。它似乎是恒星形成区域的共同组成部分,这些恒星形成区域促进了银河宜居区域内的行星系统,其丰度可与黑尔-波普彗星中的相比。甲酰胺在彗星和分子云中的存在表明该化合物可能是通过外源传递而带入地球的,一次撞击的流入流量可能高达〜0.1 mol / km〜2 / yr或0.18 mmol / m〜2。最近已提出甲酰胺作为核碱基和核酸的单碳益生元来源。这项研究表明,足够的NH_2CHO可以用于这种化学反应。

著录项

  • 来源
    《Astrobiology》 |2013年第5期|439-453|共15页
  • 作者单位

    Department of Chemistry and Steward Observatory, University of Arizona, Tucson, Arizona;

    Department of Astronomy and Steward Observatory, University of Arizona, Tucson, Arizona;

    University of Arizona 933 North Cherry Ave. Tucson, AZ 85721-0065,Department of Chemistry and Steward Observatory, University of Arizona, Tucson, Arizona,Department of Astronomy and Steward Observatory, University of Arizona, Tucson, Arizona;

  • 收录信息 美国《科学引文索引》(SCI);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Formamide; Astrobiology; Radioastronomy; ISM; Comets; Meteorites;

    机译:甲酰胺天体生物学;射电天文学;主义;彗星;陨石;

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