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Process for selective hydrogenation of ethylenically unsaturated double bonds in p polymers, aqueous polymeric dispersion, and, polymer

机译:p聚合物,水性聚合物分散体和聚合物中烯键式不饱和双键的选择性加氢方法

摘要

'' PROCESS FOR SELECTIVE HYDROGENATION OF DOUBLE LINKS ETHYLENICALLY UNSATURATED IN POLYMERS P, E, WATER POLYMERIC DISPERSION ''. The invention relates to a process for selective hydrogenation of unsaturated ethylene double bonds in polymerisers (P), whereby the polymerisers (P) are reacted with hydrogen in the presence of at least one hydrogenation catalyst, said catalyst being selected from complex rhodium and / or ruthenium salts and compounds, in an aqueous dispersion of polymerisers (P) that contain no more than 20 percent by volume of organic solvent. The invention also relates to hydrogenated polymerisation dispersions obtained according to the inventive process, and to polymerisers obtained from said polymerisate dispersions. In addition, the invention also relates to aqueous polymerisate dispersions containing polymers (P ') which have the structural elements (I), (II) and (III) according to claim 10 and have optional structural elements (IV) and / or (V) according to claim 9.
机译:''在P,E和水聚合物分散体中非饱和键合的双键选择性加氢的过程''。本发明涉及在聚合器(P)中选择性氢化不饱和乙烯双键的方法,其中使聚合器(P)在至少一种氢化催化剂的存在下与氢反应,所述催化剂选自络合铑和/或钌盐和化合物,在聚合剂(P)的水分散液中,其有机溶剂的体积含量不超过20%。本发明还涉及根据本发明方法获得的氢化聚合分散体,并且涉及由所述聚合产物分散体获得的聚合器。此外,本发明还涉及含有聚合物(P′)的水性聚合产物分散体,所述聚合物(P′)具有根据权利要求10的结构要素(I),(II)和(III),并且具有任选的结构要素(IV)和/或(V)。 ),根据权利要求9。

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