Boron and zirconium co-doped TiO_2 powders prepared through mechanical ball milling

摘要

A titania photocatalyst co-doped with boron and zirconium was prepared by mechanical ball milling. The resulting powder was characterized by XRD, XPS, SEM, and EDS. The photocatalytic performance of the powder was evaluated by degradation of methylene blue (MB) solution under UV illumination. XRD patterns were refined by Rietveld analysis to obtain accurate lattice parameters and positions of the atoms in the'crystal structure of the photocatalyst. XRD, XPS, and Rietveld analysis results indicated that mechanical ball milling successfully weaved the dopant elements into the crystal structure and distorted the lattice of TiO_2. Also, SEM micrographs confirmed that mechanical ball milling led to a decrease in average particle size of the photocatalyst. Boron and zirconium co-doped TiO_2 particles exhibited a better visible light response and photocatalytic activity than those of the mono-element doped TiO_2 (i.e. B-TiO_2 and Zr-TiO_2) and undoped TiO_2 particles. The enhanced photocatalytic activity is attributed to the synergistic effects of boron-zirconium co-doping and particle size reduction.