首页> 外文期刊>BARC Newsletter >AN INDIGENOUSLY DEVELOPED DUAL TIME OF FLIGHT MASS SPECTROMETER SETUP WITH NANOCLUSTER AND ELECTROSPRAY SOURCES FOR GAS PHASE STUDIES
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AN INDIGENOUSLY DEVELOPED DUAL TIME OF FLIGHT MASS SPECTROMETER SETUP WITH NANOCLUSTER AND ELECTROSPRAY SOURCES FOR GAS PHASE STUDIES

机译:利用气相色谱和电喷雾源建立的飞行质谱仪的本地开发双重时间

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This paper reports on the dual time-of-flight mass spectrometer coupled to a magnetron based source for metal nanoclusters and an electrospray ion source for gas phase studies, all developed indigenously. The system consists of a reflectron time-of-flight and a linear time-of-flight mass spectrometers positioned perpendicular to each other. It can distinctly measure time events separated by 1.4 nanoseconds and distinguish species on an abundance scale of 1/2000. Various applications in different studies, e.g. identification of isomers of small water clusters, simultaneous growth of positive, negative and neutral copper clusters and isotopic abundance within single cluster masses are discussed. The studies depict the compatible utility of a sophisticated home-built instrument.
机译:本文报道了双飞行时间质谱仪与基于磁控管的金属纳米团簇源和用于气相研究的电喷雾离子源的结合,所有这些都是本机开发的。该系统由反射电子飞行时间和彼此垂直放置的线性飞行时间质谱仪组成。它可以清晰地测量相隔1.4纳秒的时间事件,并以1/2000的丰度范围区分物种。在不同研究中的各种应用,例如讨论了小型水团簇的异构体的鉴定,正,负和中性铜团簇的同时生长以及单个团簇内的同位素丰度。这些研究描绘了复杂的家用仪器的兼容实用程序。

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