DGEBA/imidazolium ionic liquid systems: the influence of anions on the reactivity and properties of epoxy systems

摘要

Imidazolium salts containing BF4-, PF6-, N(CN)(2)(-), FeCl4-, or Zn-2 Cl-5(-) ionic liquids were blended with an epoxy prepolymer, dyglycidylether of bisphenol A (DGEBA) to obtain a series of compositions. To characterize the resulting mixtures and determine the influence of the imidazolium anion on the reactivity and properties of epoxy systems, we performed the following analyses and tests: (i) differential scanning calorimetry (DSC), to determine the curing reaction characteristics, (ii) in situ fourier-transform infrared spectroscopy (FTIR), to assess chemical structure changes, (iii) mechanical property testing of the hardened epoxy material, and (iv) thermogravimetric analysis (TGA). The DSC and FTIR analyses indicate that [Hmim] BF4, and [Hmim] PF6 cannot induce the epoxy ring opening reaction and thus these materials are unable to function as epoxy curing agents. In contrast, the imidazolium ionic liquids [Hmim] FeCl4, [Hmim] N(CN)(2), and [Hmim] Zn-2 Cl-5 independently promote the epoxy ring opening reaction. TGA analyses show that the cured DGEBA/[Hmim] Zn-2 Cl-5 system exhibits thermal stability similar to the cured DGEBA/[Hmim] FeCl4. These results can provide an essential reference not only for studying the synergistic effect of [C-6 mim] FeCl4/mixed-amines on the curing process of epoxy systems and the mechanism of the ring opening of epoxides with [C-6 mim] FeCl4/mixed-amines, but also for designing new epoxy curing systems.