Mechanism of the Reaction of Water Oxidation by Cerium(IV) Compounds Catalyzed by Ruthenium Octanuclear Clusters

摘要

The kinetics and mechanism of the action of octanuclear ruthenium catalysts for the oxidation of water by Ce(IV) compounds in artificial photosynthesis are studied. The catalysts are obtained from K-3[Ru-2(mu-N)Cl-8] center dot 2H(2)O complex via self-organization. It is established that [Ru-(mu-N)-Ru](4)octanuclear clusters form upon the tetramerization of the binuclear nitride complex and catalyze the eight-electron oxidation of water to two oxygen molecules. Only tetranuclear clusters that oxidize water in four-electron reaction to one oxygen molecule form at high temperatures (>60 degrees C).