Enhancing the electrical conductivity of carbon-nanotube-based transparent conductive films using functionalized few-walled carbon nanotubes decorated with palladium nanoparticles as fillers

摘要

This work demonstrates the processing and characterization of the transparent and highly electrically conductive film using few-walled carbon nanotubes (FWCNTs) decorated with Pd nanoparticles as fillers. The approach included functionalizing the FWCNTs, immersing them in an aqueous solution of palladate salts, and subsequently subjecting them to a reduction reaction in H_2. Field-emission scanning electron microscopy and transmission electron microscopy images showed that the functionalized FWCNTs (f-FWCNTs) were decorated with uniform and homogeneous Pd nanoparticles with an average diameter of 5 nm. A shift of the G-band to a higher frequency in the Raman spectra of the Pd-decorated f-FWCNTs (Pd@f-FWCNTs) illustrates that the p-type doping effect was enhanced. X-ray photoelectron spectroscopy and energy-dispersive X-ray spectroscopy showed that PdCl_2 was the primary decoration compound on the f-FWCNTs prior to the reduction reaction and that Pd nanoparticles were the only decorated nanoparticles after H_2 reduction. The contact resistance between the metallic materials and the semiconducting CNTs in FWCNTs, controlled by the Schottky barrier, was significantly decreased compared to the pristine FWCNTs. The decrease in contact resistance is attributed to the 0.26 eV increase of the work function of the Pd@f-FWCNTs. Extremely low sheet resistance of 274 ohm/sq of the poly(ethylene terephthalate) substrates coated with Pd@f-FWCNTs was attained, which was 1/25 the resistance exhibited by those coated with FWCNTs, whereas the same optical transmittance of 81.65% at a wavelength of 550 nm was maintained.