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首页> 外文期刊>The Journal of Chemical Physics >Double-diamond phase in amphiphilic systems confined between parallel walls
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Double-diamond phase in amphiphilic systems confined between parallel walls

机译:两亲体系中的双金刚石相局限于平行壁之间

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摘要

Effects of confinement on the cubic bicontinuous phase with double-diamond symmetry (D) are studied. We focus on a slit geometry and on highly selective external walls. We show that the period of the solvation force in different systems containing amphiphilic molecules can be found on simple symmetry grounds. The simple symmetry-based predictions are verified by explicit calculations in a lattice model for oil-water-surfactant mixtures. The explicit results obtained within the model allow for a detailed description of the effects of the confinement on the structure of the D phase. The structure of the D phase with the face of the unit cell parallel to the external wall is shown and discussed for slits ranging from very narrow to very large ones.
机译:研究了约束对双金刚石对称立方双连续相的影响(D)。我们专注于狭缝几何形状和高度选择性的外墙。我们表明,在包含两亲分子的不同系统中,溶剂化作用力的周期可以在简单的对称基础上找到。在油水表面活性剂混合物的晶格模型中,通过显式计算对基于对称性的简单预测进行了验证。在模型中获得的显式结果允许详细描述约束对D相结构的影响。示出并讨论了D相的结构,其中晶胞的表面平行于外壁,狭缝的范围从非常窄到非常大。

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