Regioselective nucleophilic substitution reaction of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin

Masaaki Suzuki; Soji Shimizu; Yi-Young Shin; Atsuhiro Osuka

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Regioselective nucleophilic substitution reaction of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin

机译：中六（五氟苯基）取代的[26]六卟啉的区域选择性亲核取代反应

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摘要

Reaction of various alkoxides led to the selective replacement of the p-fluorine substituents of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin. Reaction with isopropyl amine gave meso-hexakis(4-isopropylamino-2,3,5,6-tetrafluorophenyl) substituted [26]hexaphyrin.

机译：各种醇盐的反应导致中六（五氟苯基）取代的[26]六卟啉的对氟取代基的选择性取代。与异丙胺反应，得到间-六（4-异丙氨基-2,3,5,6-四氟苯基）取代的[26]六卟啉。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2003年第24期|共5页
作者
Masaaki Suzuki; Soji Shimizu; Yi-Young Shin; Atsuhiro Osuka;
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正文语种 eng
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porphyrinoids; expanded porphyrin; nucleophilic substitution;

机译：卟啉类;膨胀卟啉;亲核取代;

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1. Regioselective nucleophilic substitution reaction of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin [J] . Masaaki Suzuki, Soji Shimizu, Yi-Young Shin, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2003,第24期

机译：中六（五氟苯基）取代的[26]六卟啉的区域选择性亲核取代反应
2. M?bius aromatic palladium(II) complexes of a β-tetraphenyl meso-hexakis(pentafluorophenyl) substituted hexaphyrin(1.1.1.1.1.1) [J] . Koide T., Osuka A. Bulletin of the Chemical Society of Japan . 2010,第8期

机译：β-四苯基内六六（五氟苯基）取代的六氢卟啉的Mbius芳族钯（II）配合物（1.1.1.1.1.1）
3. Regioselective Nucleophilic Aromatic Substitution Reaction of meso-Pentafluorophenyl-Substituted Porphyrinoids with Alcohols [J] . Golf Hartwig R. A., Reissig Hans-Ulrich, Wiehe Arno European journal of organic chemistry . 2015,第7期

机译：中五氟苯基取代卟啉类化合物与醇的区域选择性亲核芳香取代反应
4. Michael Addition Reactions between Nucleophilic GlycineEquivalents and Acrylic Acid Derivatives as a Practicaland Generalized Approach to the Asymmetric Synthesisof II-Substituted-a-Amino Acids [C] . Vadim A. Soloshonok, Hisanori Ueki, Trevor K. Ellis ACS symposium asymmetric synthesis and application of α-amino acids . 2009

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5. Synthesis of cyclic ketene nitrogen,oxygen-acetals and their reactions with isocyanates and isothiocyanates. Nucleophilic substitutions in ionic liquids. [D] . Liu, Zhuqing. 2003

机译：环状烯酮氮，氧-乙缩醛的合成及其与异氰酸酯和异硫氰酸酯的反应。离子液体中的亲核取代。
6. Efficient synthesis of 5-substituted 2-aryl-6-cyanoindolizines via nucleophilic substitution reactions [O] . Eugene V Babaev, Natalya I Vasilevich, Anna S Ivushkina 2005

机译：通过亲核取代反应高效合成5-取代的2-芳基-6-氰基吲哚嗪
7. The Profound Effect of Fluorine Substitution on the Reactivity and Regioselectivity of Nucleophilic Substitution Reactions of Strained Heterocycles. A Study of Aziridine and Its Derivatives [O] . -1

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8. Reactions in Microemulsion Media. Nucleophilic Substitution Reactions of Benzyl and p-Alkylbenzyl Chlorides [R] . Martin, C. A., McCrann, P. M., Ward, M. D., 1984

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Regioselective nucleophilic substitution reaction of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin

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