Formation of methylchloroaluminium alkanethiolates, MeAl(SR)Cl, and dichloroaluminium alkanethiolates, Cl2AlSR, from methylaluminium dichloride and trimethylsilyl alkanethiolates, Me3SiSR

摘要

Depending on the reaction conditions methylaluminium dichloride, MeAlCl2, and trimethylsilyl alkanethiolates, Me3SiSR, give dichloroaluminium alkanethiolates, Cl2AlSR with R = Me and Et or methylchloroaluminium alkanethiolates, MeAl(SR)Cl with R = Me, Et, and i-Pr. The reaction pathways are described and IR and H-1 NMR spectroscopic data are presented. [References: 21]