首页> 外文期刊>The Journal of Organic Chemistry >Regio- and stereoselective synthesis of cyclic imidates via electrophilic cyclization of 2-(1-alkynyl)benzamides. A correction
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Regio- and stereoselective synthesis of cyclic imidates via electrophilic cyclization of 2-(1-alkynyl)benzamides. A correction

机译:通过2-(1-炔基)苯甲酰胺的亲电环化,对环酰亚胺进行区域和立体选择性合成。更正

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摘要

The electrophilic cyclization of 2-(1-alkynyl)benzamides affords high yields of cyclic imidates, instead of the previously reported isoindolin-1-ones, where cyclization proceeds on the oxygen of the carbonyl group rather than the nitrogen of the amide functionality. X-ray crystallography and spectroscopic techniques have been used to characterize the products. A correction is hereby provided in order to rectify the previous misassignment of structure.
机译:2-(1-炔基)苯甲酰胺的亲电环化反应可提供高产率的环状酰亚胺,而不是先前报道的异吲哚啉-1-酮,其中环化反应在羰基的氧而不是酰胺官能团的氮上进行。 X射线晶体学和光谱技术已用于表征产物。在此提供校正,以校正先前的结构错配。

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