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A small system grand ensemble method for the study of hard-particle systems

机译:用于研究硬粒子系统的小系统整体集成方法

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This paper introduces an alternative statistical geometrical method for the evaluation of the thermodynamic properties of hard-particle systems. We develop a general theory which allows one to express average quantities in terms of geometrical "measurables." The theory is tested with the known exact results for the one-dimensional hard rod fluid. We also discuss the potential benefits of the theory in efficiently calculating the chemical potential and pressure (using Monte Carlo methods) of dense hard-particle fluids in two and three dimensions. (C) 1998 American Institute of Physics. [References: 19]
机译:本文介绍了一种用于评估硬粒子系统热力学性质的替代统计几何方法。我们开发了一种通用理论,该理论允许人们用几何“可测量值”表示平均数量。用已知的一维硬棒流体精确结果测试了该理论。我们还将讨论该理论在二维和三维中有效计算致密硬颗粒流体的化学势和压力(使用蒙特卡洛方法)的潜在优势。 (C)1998美国物理研究所。 [参考:19]

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