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Effect of thermal treatment on the structure of PCC particles

机译:热处理对PCC颗粒结构的影响

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The controlled combustion of paper is normally used to determine the filler content of paper.It can also be a valuable tool to isolate the mineral particles for extra characterization or additional applications.However,the ashing temperature greatly affects the filler particles.The main goal of this study was to analyze the effects of paper calcinations on the intrinsic properties of precipitated calcium carbonate filler (PCC) at distinct temperatures,from 400 deg C up to 1000 deg C.We characterized the size,density,surface area,porosity,chemical composition,color,and electrostatic charge of the original PCC particles and the ash.The experimental results revealed that for a calcination temperature of 400 deg C,the size,specific surface area,and porosity of the ash are similar to those of the PCC filler before being incorporated in paper.Other important filler properties,such as color and electrical charge,are much different.To overcome this disadvantage,higher ashing temperatures need to be used.This study has demonstrated that 600 deg C is the optimum temperature for isolating the paper fillers,without the collapse of the PCC structure,so that their physical,chemical,optical,and electrical characteristics are adequately balanced and not too different from those of the original particles.
机译:纸的受控燃烧通常用于确定纸中的填料含量。它还可以作为隔离矿物颗粒以进行额外表征或其他应用的有价值的工具。然而,灰化温度会极大地影响填料颗粒。本研究旨在分析纸煅烧对400℃至1000℃不同温度下沉淀碳酸钙填料(PCC)固有特性的影响。我们表征了尺寸,密度,表面积,孔隙率,化学成分实验结果表明,煅烧温度为400摄氏度时,灰分的大小,比表面积和孔隙率与PCC填料之前的相似。其他重要的填料性能(例如颜色和电荷)相差很大。要克服此缺点,需要更高的灰化温度该研究表明,在不使PCC结构塌陷的情况下,隔离纸填料的最佳温度为600℃,因此它们的物理,化学,光学和电气特性得到了适当的平衡,并且与那些原始粒子。

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