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首页> 外文期刊>IUCrData >trans-Bis{2-[bis(1H-pyrazol-1-yl)methyl]-1-methyl-1H-benzimidazole}-iron(II) bis(perchlorate) aceto-nitrile disolvate
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trans-Bis{2-[bis(1H-pyrazol-1-yl)methyl]-1-methyl-1H-benzimidazole}-iron(II) bis(perchlorate) aceto-nitrile disolvate

机译:Trans-Bis {2- [双(1H-吡唑-1-基)甲基] -1-甲基-1H-苯并咪唑} - 铁(II)双(高氯酸盐)乙酰丁腈

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摘要

In the structure of the title complex, [Fe(C 15 H 14 N 6 ) 2 ](ClO 4 ) 2 ·2C 2 H 3 N, the asymmetric unit contains one complete ligand mol-ecule, one perchlorate and one aceto-nitrile solvent mol-ecule. The iron(II) atom, situated on an inversion centre, is surrounded by six nitro-gen atoms from two ligands in an octa-hedral coordination sphere in which the two benzimidazole units adopt a trans -configuration. The crystal structure is stablized by extensive weak C—H?O and C—H?N inter-actions.
机译:在标题复合物的结构中,[Fe(C 15 H 14 N 6)2](CLO 4)2·2C 2 H 3 N,不对称单元含有一个完整的配体摩尔饼,一种高氯酸盐和一种丙酮腈溶剂摩尔肉体。位于倒置中心的铁(II)原子由来自两个配体的六个硝基-Ge原子包围,其中两个苯并咪唑单元采用反式固化。晶体结构通过广泛的弱C-H?O和C-H?n互动。

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