Nucleophilic Substitution of P-Stereogenic Chlorophosphines and Stereoselective Conversions of Diastereomeric Secondary Phosphine Oxides to Tertiary Phosphine

摘要

Chiral tertiary phosphines attract extensive attention because of their important applications in asymmetric synthesis, as ligands of metallic catalysts and as organocatalysts. However, the compounds are acquired usually form multistep conversions or tedious resolutions.