Effect of Combustion Products on Detonation Velocities

摘要

Pressure gain combustion has received increased interest in recent years because of the potential for increased thermodynamic efficiencies in propulsion and power generation applications. In pressure gain devices, mixing of fuel and oxidizer with combustion products can occur in the combustion chamber as the reactants are injected and the exhaust products are purged. Most research, however, considers only fresh reactants. This is significant because it can result in decreased detonation velocities. Laminar flame speed calculations show that dilution with combustion products can reduce the flame speed as a consequence of both dilution and chemistry effects. The objective of this study is to identify the effects of dilution with combustion products on detonation velocities, expanding on the results for laminar flame speed calculations. Experiments were performed using a pulse detonation engine instrumented with photodiodes to measure detonation velocities. Sonic orifices were used to meter mass flow rates of fuel (C_3H_8), oxidizer (N_2O), and combustion products (CO_2) or inert diluents (N_2). The experiments were performed such that the sensible enthalpy of the diluents was matched, thus observed velocity sensitivities indicate a chemical kinetic effect. The data indicates that non-inert diluents demonstrate a suppression in detonation velocities resulting from chemical kinetic effects. Specifically, testing with CO_2 showed a significant velocity deficit when compared to inert N_2.