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Preparation of spinel Li{sub}(1+x-y)Zn{sub}xMn{sub}(2-y)O{sub}4 and its Li intercalation behavior

机译：尖晶石Li {Sub}（1 + X-Y）Zn {Sub} XMN {Sub}（2-Y）O {Sub} 4的制备及其Li嵌入行为

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Zn doped lithium manganese oxides with a space group of F{sub}(d3m) have been prepared by rapid cooling after heating at 700-800 °C in oxygen. Pure Zn doped spinet with Zn/Mn=0.05 forms in the range of 0.43

机译：通过在700-800℃的氧中加热后，通过快速冷却制备Zn掺杂锂锰氧化物，其具有F {}（D3M）的空间组。具有Zn / Mn的纯Zn掺杂丝丝丝丝梗在0.43（= li /（Mn + Zn）<0.523的范围内。Zn掺杂尖晶石的RIETVELD细化的结果表明Zn离子占据棘爪的4A位点结构。高加热温度和锂含量降低（下部N）可有效地增加Zn掺杂纺丝夹的能力。该棘爪在50℃下显示出优异的循环性能。

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《ECS Meeting》|2001年||共6页
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Hideyuki Noguchi; Hiroyoshi Nakamura;
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Preparation of spinel Li{sub}(1+x-y)Zn{sub}xMn{sub}(2-y)O{sub}4 and its Li intercalation behavior

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