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Modification of a carbon electrode surface by cold plasma treatment for electric duble layer capacitors

机译:用冷等离子体处理对碳电极表面进行电气双层电容器的修改

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Activated carbon fiber cloth (ACFC) electrodes whose surface was modified by "pulsed cold plasma", i.e., low-temperature plasma generated by a pulsed electric power in argon-oxygen mixed gas at a reduced pressure, were applied to electric double layer (EDL) capacitors with an organic electrolyte composed of propylene carbonate and tetraethylammonium tetrafluoroborate (TEABF_4). The treatgment of the ACFC electrodes with the pulsed cold plasma increased toal capacitance in the EDL capacitors. The observed increase in the total capaccitance was ascribed mainly to an ascertained increase in capacitance of a negative ACFC electrode involving TEA~+ cation adsorption/desorption with the cold plasma treatment. No obvious increase in capacitance of a positive ACFC electrode involving BF_4~- anion adsorption/desorption was observed with the plasma treatment. The chemical and electrochemical characteristics of a treated ACFC interface were found to be favorable for TEA~+ cation adsportion/desorption.
机译:通过“脉冲冷等离子体”改性表面的活性炭纤维布(ACFC)电极,即通过氩气混合气体中的脉冲电力产生的低温等离子体,施加到电双层(EDL) )具有由碳酸亚丙酯和四乙基四氟硼酸丙酯(TeaBF_4)组成的有机电解质的电容器。具有脉冲冷等离子体的ACFC电极对EDL电容器中的脉冲冷等离子体增加。总电容器的观察到的增加主要归因于涉及涉及茶〜+阳离子吸附/解吸的负ACFC电极的电容的所确定的电容增加。通过等离子体处理观察到涉及BF_4〜 - 阴离子吸附/解吸的正ACFC电极的电容的显而易见。发现治疗的ACFC界面的化学和电化学特征是有利于茶〜+阳离子伴随/解吸的。

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