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Syntheses of Anionic Bisphosphineimide Complexes as Novel Metallachelate Ligands and Their Coordination Complexes

机译：阴离子二膦酰亚胺配合物作为新型金属丙烯酸盐配体及其配位复合物合成

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The treatment with MeLi of the cationic bis(aminophosphite)iron complex,[Cp~*(CO)Fe-{P(OMe)_2(NHPh)}_2]PF_6) yielded the anionic bis(phosphineimide)iron complex,Li[Cp~*(CO)Fe-{P(NPh)(OMe)_2}_2],which serves as a novel N-N chelating ligand toward several metals to form binuclear complexes.Syntheses and X-ray crystal structures of Rh and Al complexes of the metalloligand are discussed.

机译：用阳离子双（氨基磷酸盐）铁络合物的熔融处理，[CP〜*（CO）Fe- {P（OME）_2（NHPH）} _ 2] PF_6）产生阴离子双（膦酰亚胺）铁络合物，LI [CP 〜*（CO）Fe- {P（NPH）（OME）_2} _2]，其用作朝向几种金属的新型NN螯合配体，以形成Binuclect络合物。Rh和Al络合物的合成和X射线晶体结构讨论了Metalloligand。

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《Symposium on Organometallic Chemistry》|2004年||共2页
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Michio Uragaki; Kazuyuki Kubo; Takashi Akimoto; Katsuhiko Miyoshi;
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Syntheses of Anionic Bisphosphineimide Complexes as Novel Metallachelate Ligands and Their Coordination Complexes

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