首页> 外国专利> Method for adhering noble metal to carbon steel member of nuclear power plant and method for inhibiting adhesion of radionuclide to carbon steel member of nuclear power plant

Method for adhering noble metal to carbon steel member of nuclear power plant and method for inhibiting adhesion of radionuclide to carbon steel member of nuclear power plant

机译:将贵金属粘附到核电站碳钢构件的方法及抑制放射性核素粘附到核电站碳钢成员的方法

摘要

Provided is a method of attaching a noble metal to a carbon steel member of a nuclear power plant, which can reduce the time required for forming a nickel metal film for attaching the noble metal on the carbon steel member. A film forming apparatus is connected to a purification system pipe, which is made of carbon steel, of a BWR plant (S1). A pH buffer solution is injected to obtain the pH 4.0 of the film forming aqueous solution (S4). An aqueous solution of nickel formate is injected into the film forming aqueous solution (S5), and a reducing agent is further injected (S5). A film forming aqueous solution including the pH buffer solution, nickel ions and the reducing agent is supplied into the purification system pipe to form a nickel metal film on the inner surface thereof. After the formic acid and the reducing agent in the film forming aqueous solution are decomposed (S8), injection of platinum ions (S10) and injection of the reducing agent (S11) are carried out, and the aqueous solution including platinum ions and the reducing agent is brought into contact with the surface of the nickel metal film formed on the inner surface of the purification system pipe to attach platinum to the surface of the nickel metal film.
机译:提供了一种将贵金属连接到核电站的碳钢构件的方法,这可以减少形成镍金属膜所需的时间,用于将贵金属在碳钢构件上附着。成膜装置连接到BWR植物的碳钢制成的净化系统管(S1)。注入pH缓冲溶液以获得成膜水溶液的pH 4.0(S4)。将镍甲酸酯的水溶液注入成膜水溶液(S5),进一步注射还原剂(S5)。将包含pH缓冲溶液,镍离子和还原剂的膜形成水溶液供应到净化系统管中,以在其内表面上形成镍金属膜。在成膜水溶液中的甲酸和还原剂分解后(S8),进行铂离子(S10)和注射还原剂(S11),以及包括铂离子的水溶液和还原剂使试剂与形成在净化系统管的内表面上形成的镍金属膜的表面接触以将铂连接到镍金属膜的表面上。

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