首页>
外国专利>
A method for the preparation of finely divided form infusible and insoluble melamine formaldehyde condensation products
A method for the preparation of finely divided form infusible and insoluble melamine formaldehyde condensation products
展开▼
机译:一种细分形式的难溶和不溶三聚氰胺甲醛缩合产物的制备方法
展开▼
页面导航
摘要
著录项
相似文献
摘要
Infusible and insoluble melamine-formaldehyde condensation products having a mean particle size 1m are prepared by reacting an aqueous solution of melamine and formaldehyde or an aqueous solution of a melamine-formaldehyde precondensate, in the presence of a protective colloid in the pH range 6 to 8 until a solid phase is formed. Reaction is preferably carried out at elevated temperature, e.g. at the boiling point of the solution. 1.5 to 6 mols. of HCHO may be used per mol. of melamine. Other aminoplast forming compounds (e.g. urea and its derivatives and other amino-triazines) may also be present. Examples of protective colloids are starch, tragacanth, gelatine, agar,-agar, polyvinyl alcohol, the sodium salt of carboxmethylcellulose and a hydrolysed polymer of maleic anhydride and styrene. The amount of protective colloid used may be 0.1 to 10% by wt. based on the total amount of aqueous reaction mixture. The starting solution may contain from 5 to 25% by wt. of resin-forming constituents. The precipitation reaction may be carried out at the boiling point of the reaction mixture.
展开▼