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Process for the synthesis of zeolites with aluminosilicate frameworks belonging to the faujasite family, the products obtained and their use in adsorption and catalysis

机译:具有八面沸石家族的具有铝硅酸盐骨架的沸石的合成方法,所得产物及其在吸附和催化中的用途

摘要

An aluminosilicate gel containing a structuring agent ST and having a composition suitable for crystallising to a zeolite of the structural group faujasite is prepared and the said gel is then subjected to a crystallisation in order to form a precursor of the zeolite consisting of the said zeolite containing the structuring agent ST in its cavities and channels and the zeolite is produced by calcination of the said precursor. The structuring agent ST consists of at least one compound chosen from the polyoxaalkyl and/or polyoxaarylamines of general formula: H(3-y)N(CmH2m-1X-O)n-Ry (I in which X denotes a hydrogen atom, an -OH radical or an alkyl or aryl group, which can be different from one unit to the next, R represents a hydrogen atom or a C1 to C3 alkyl radical and which can be different from one chain to the next, m is equal to 2 or 3 and can be different from one unit to the next, n is a number ranging from 1 to 4 and y is a number ranging from 1 to 3.
机译:制备含有结构剂ST并且具有适合于结晶成八面沸石的沸石的组成的铝硅酸盐凝胶,然后使所述凝胶结晶以形成由所述含沸石的沸石组成的沸石的前体。在其空腔和通道中形成结构剂ST,并通过煅烧所述前体来生产沸石。结构化剂ST由至少一种选自通式为H(3-y)N(CmH2m-1X-O)n-Ry的聚氧杂烷基和/或聚氧杂芳基的化合物组成(I>其中X表示氢原子, -OH基团或烷基或芳基,其可与一个单元不同; R表示氢原子或C1-C3烷基,且可与一个链至下一个不同,m等于2或3,并且一个单位与另一个单位可以不同,n是1到4的数字,y是1到3的数字。

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