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Method of recovering sulfur component in sulfur recovery process

机译:硫磺回收过程中硫磺成分的回收方法

摘要

In the present invention, by a process that (1) reacts SO 2 (24) gas rich H 2 S content of a gas rich H 2 S content of the reactor to the presence of a catalyst and organic solvent (101) in 2 S H is removed, sulfur (60) is generated. Is removed from the reactor (101) (5) H 2 S-containing gas, to produce (10) (104), the combustion gas high SO 2 content is combusted. Preferably, the combustion gas to also include sulfur vapor and water vapor, the reactor exhaust gas is burned in oxygen of substoichiometric amounts. Combustion gas, is cooled by indirect heat exchange, or (234) direct cooling, generating (31) a (Wackenroder solution, for example) an aqueous stream comprising a polythionic acid and solid sulfur which water and suspended primarily , the aqueous stream is subjected to cooling of the reaction 2 H 2 S-SO. Problems associated with the generation and processing of Wackenroder solution is resolved, sulfur valuables in these materials are recovered.
机译:在本发明中,通过使(1)中的SO 2(24)气体中的H 2S 中的气体中的H 2S 含量高的方法进行处理。除去在 2 S H中存在催化剂和有机溶剂(101)的反应器中的Sub>含量,生成硫(60)。从反应器(101)中除去(5)含H 2 的气体,生成(10)(104),燃烧高SO 2 含量的燃烧气体。优选地,燃烧气体还包括硫蒸气和水蒸气,反应器排气在亚化学计量量的氧气中燃烧。通过间接热交换或(234)直接冷却来冷却燃烧气体,从而产生(31)(例如,Wackenroder溶液)包含聚硫酸和固体硫的水流,该水首先悬浮并悬浮,该水流经过冷却反应 2 H 2 S-SO。解决了与Wackenroder溶液产生和处理有关的问题,回收了这些材料中的硫贵重金属。

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