METHOD FOR CONTROLLING SELF-ASSEMBLED SRUCTURE OF POLY(3-HEXYLTHIOPHENE)-BASED BLOCK COPOLYMER

摘要

Provided is a method for controlling a self-assembled structure of a poly(3-hexylthiophene)-based block copolymer, including: providing a polymer composition containing a block copolymer having a π-conjugated poly(3-hexylthiophene) polymer and a non-conjugated polymer introduced thereto, and a solvent; and coating the polymer composition onto a substrate.;According to the method disclosed herein, it is possible to control a self-assembled structure of a poly(3-hexylthiophene)-based block copolymer merely by a relatively simple process including coating the poly(3-hexylthiophene)-based block copolymer onto a substrate with a selected solvent. In this manner, it is possible to control the alignment of conductive domains in the block copolymer so that it is suitable for various organic electronic devices. In addition, the self-assembled polymer structure having various self-assembled structures controlled selectively by the method may be applied to organic electronic devices for designing and developing high-quality devices.