首页> 外国专利> Method for producing structure having aromatic polymer bonded to substrate, structure having aromatic polymer chain bonded to conductive substrate, and electronic device including the structure

Method for producing structure having aromatic polymer bonded to substrate, structure having aromatic polymer chain bonded to conductive substrate, and electronic device including the structure

机译:制备具有结合到基底上的芳族聚合物的结构的方法,具有结合到导电基底上的芳族聚合物链的结构和包括该结构的电子器件

摘要

Disclosed is a method for efficiently producing a structure wherein an aromatic polymer is bonded to a base. Also disclosed is such a structure wherein the base is electrically conductive. Specifically disclosed is a method for producing a structure, which comprises a step for polycondensing an aromatic compound represented by the formula (I) below in the presence of a polymerization catalyst and a base having a group represented by the formula (II) below. (In the formula (I), Ar represents a divalent group composed of an aromatic ring; X represents a halogen atom or the like; Y represents an oxygen atom, a sulfur atom, an imino group or the like; n represents 0 or 1; and M represents a hydrogen atom, -B(OQ 1 ) 2 (wherein Q 1 represents a hydrogen atom, a hydrocarbon group or the like) or the like.) €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€”Ar a €”(X a ) p €ƒ€ƒ€ƒ€ƒ€ƒ(II) (In the formula (II), Ar a represents a group having a valence of (p + 1) and composed of an aromatic ring; X a represents a halogen atom or a monovalent group expressed as -SO 3 Q a (wherein Q a represents a substituted or unsubstituted hydrocarbon group); p represents an integer not less than 1, and when p is an integer not less than 2, the plurality of X a' s may be the same as or different from each other.)
机译:公开了一种有效地生产其中芳族聚合物键合到基体上的结构的方法。还公开了这样的结构,其中基部是导电的。具体公开了一种用于制造结构的方法,该方法包括以下步骤:在聚合催化剂和具有由下式(II)表示的基团的碱的存在下使由下式(I)表示的芳族化合物缩聚的步骤。(式(I)中,Ar表示由芳香族环构成的二价基团; X表示卤原子等; Y表示氧原子,硫原子,亚氨基等; n表示0或1。 ;和M代表氢原子,-B(OQ 1)2(其中Q 1代表氢原子,烃基等)等。“ Ar a€”(X a)p€ƒ€ƒ€ƒ€ƒ(II)(式(II)中,Ar a表示化合价为(p + 1)且由芳香环构成的基团; X a表示卤原子或表示为-SO 3 Q a的一价基团(其中,Q a表示取代或未取代的烃基); p表示不小于1的整数,并且当p为不小于2的整数时,多个X a可以彼此相同或不同。)

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