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Polyvinylidene Fluoride Resin Film, Multilayer Film, Backsheet for Solar Cell Module and Production Process of Film

机译:聚偏二氟乙烯树脂薄膜,多层薄膜,太阳能电池组件用背板及其制造工艺

摘要

The invention provides a polyvinylidene fluoride resin (PVDF) film in which a crystal structure determined from an absorbance by an infrared absorption spectrum is such that a proportion of a β-type crystal is 10% or more based on the sum total of an α-type crystal and the β-type crystal, further preferably a film whose tensile modulus in TD at 120° C. is 90 MPa or less, or a film in which a ratio of its tensile modulus in TD at a temperature of 100° C. to its tensile modulus in TD at a temperature of 23° C. is 4% or less, in particular an extruded film, a backsheet for solar cell module, which comprises the film, and a production process of the film, which comprises quenching a PVDF sheet-shaped material melt-extruded at 5 to 70° C. and preferably then subjecting the quenched material to a heat treatment.
机译:本发明提供一种聚偏二氟乙烯树脂(PVDF)膜,其中根据红外吸收光谱的吸光率确定的晶体结构使得β型晶体的比例基于α-的总和为10%以上。 α型晶体和β型晶体,进一步优选在120℃下的TD中的拉伸模量为90MPa以下的膜或在100℃的温度下的TD中的拉伸模量的比的膜。其在23℃的温度下在TD中的拉伸模量为4%或更低,特别是挤出膜,包括该膜的太阳能电池模块用背板以及包括淬火后的膜的制造方法将PVDF片状材料在5至70℃下熔融挤出,然后优选对淬火后的材料进行热处理。

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