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Alumina support, a process for preparing the support, a silver catalyst prepared from the support, and use thereof

机译:氧化铝载体,制备载体的方法,由该载体制备的银催化剂及其用途

摘要

An alumina support comprises alpha-alumina as the main crystal phase of its backbone, and having a specific surface area of no higher than 3.0 m2/g, a pore volume ranging from 0.3 ml/g to 0.8 ml/g, an alkaline earth metal content ranging from 0.05% to 2.0% by weight of the support, wherein the support has such properties that treating the support with an aqueous oxalic acid solution having a concentration ranging from 0.4% to 2.0% by weight and having twice the weight of the support for 30 minutes can produce a leach liquor having an aluminum content of no higher than 60 μg/mL, a sodium content of no higher than 20 μg/mL, and a silicon content of no higher than 40 μg/mL. Processes for preparing the alumina support, silver catalysts comprising the alumina support, and methods of preparing ethylene oxide by ethylene oxidation using the silver catalyst are also disclosed herein.
机译:氧化铝载体包含α-氧化铝作为其主链的主晶相,比表面积不大于3.0 m 2 / g,孔体积为0.3 ml / g至0.8毫升/克,碱土金属含量为载体重量的0.05%至2.0%,其中载体具有的特性使得可以用浓度为0.4%至2.0%的草酸水溶液处理载体并且具有两倍于载体重量的30分钟可以生产出浸出液,其铝含量不超过60μg/ mL,钠含量不超过20μg/ mL,硅含量不超过40微克/毫升本文还公开了制备氧化铝载体的方法,包含氧化铝载体的银催化剂以及使用银催化剂通过乙烯氧化制备环氧乙烷的方法。

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