首页> 外国专利> process of producing alkyl esters from the reaction of fatty acids and / or vegetable oils and / or animal fats and / or waste oil fats. glycerin production as a co-product of transesterification of vegetable oils and / or animal fats and / or shortened alcohols and residual oils using catalyst

process of producing alkyl esters from the reaction of fatty acids and / or vegetable oils and / or animal fats and / or waste oil fats. glycerin production as a co-product of transesterification of vegetable oils and / or animal fats and / or shortened alcohols and residual oils using catalyst

机译:由脂肪酸和/或植物油和/或动物脂肪和/或废油脂肪反应生成烷基酯的方法。使用催化剂将甘油作为植物油和/或动物脂肪和/或起酥油和残油的酯交换反应的副产物

摘要

process of producing alkyl esters from the reaction of fatty acids and / or vegetable oils and / or animal fats and / or residual fats and oils. Glycerin production as a co-product of transesterification of vegetable oils and / or animal fats and / or residual fats and oils with short chain alcohols using a catalyst, the present invention reports the use of m2 (s04) 2 compounds, where m represents a series of transition metals, as catalysts in high activity heterogeneous processes, useful in obtaining alkyl esters from fatty acid esterification and / or transesterification of vegetable oils, referentially used in biofuels production and, more preferably also from biodiesel. Catalysts are obtained from simple and inexpensive experimental procedures and high purity alkyl esters in reactions with conversions greater than 90%. This invention also encompasses the recovery and reuse of catalysts after proper treatment as they are insoluble and stable compounds after their use in esterification and / or transesterification catalysis. furthermore, the product treatment steps are simplified, the alkyl esters being obtained with high purity even without any common treatment step in homogeneous route processes.
机译:由脂肪酸和/或植物油和/或动物脂肪和/或残余脂肪和油的反应生产烷基酯的方法。使用催化剂将甘油作为植物油和/或动物脂肪和/或残余脂肪和油与短链醇进行酯交换的副产物,本发明报道了使用m2(s04)2化合物,其中m代表系列过渡金属,作为高活性非均相过程中的催化剂,可用于从植物油的脂肪酸酯化和/或酯交换反应中获得烷基酯,这些烃可参考地用于生物燃料生产,更优选地还用于生物柴油。通过简单且廉价的实验程序和高纯度烷基酯,以大于90%的转化率获得催化剂。本发明还包括经过适当处理的催化剂的回收和再利用,因为它们在酯化和/或酯交换催化中使用后是不溶和稳定的化合物。此外,简化了产物处理步骤,即使在均相路线方法中无需任何常规处理步骤,也能以高纯度获得烷基酯。

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