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HEAVY OIL PRODUCTS IN THE META-STABLE CONDITION THERMAL CRACKING METHOD AND INSTALLATION

机译:亚稳态热裂解方法中的重油产品及安装

摘要

FIELD: oil and gas industry.;SUBSTANCE: invention relates to the oil refining and petrochemical industry and can be used, in particular, to increase the heavy oil feedstock processing depth. Heavy petroleum products thermal cracking method comprises the high molecular weight feedstock feeding to the heating zone, the feedstock heating to subcritical temperature, conducting the controlled intensive thermal cracking process, formed light fractions separation, feeding the remainder to mixing with the feedstock stream directed to the heating zone, wherein the cracking is performed in the feedstock metastable state, at that, the feedstock is transferred by heating under low pressure into the metastable state with enabling high cracking rate temperature Tm=500–790 °C, and is maintained in this state for the period of time τm, at that, the Tm value should be below the maximum superheating temperature Tp, the Tm/Tp ratio is set from the condition, that the metastable state τg lifetime was more than cracking time τk, by the feedstock of temperature change mode T by time τ controlling by the given function T=f(τ), performing heating in two stages, preliminary and rapid heating, at that, at the first stage, the temperature increases from the initial value T0 to temperature T1, which lies below the feedstock boiling point beginning, but does not exceed its thermal stability temperature (350–360 °C), at the second stage, the feedstock is rapidly superheated to the metastable state during time from 0.5 to 5 times of the liquid medium's lifetime values in the given state, observing the τgτmτk condition. Heavy oil products thermal cracking unit includes the feedstock to the heating zone supply system, unit for the feedstock heating to the required temperature and ensuring its thermal cracking, the cracking process control device, unit for the remainder returning for the mixing with the feedstock stream, wherein for the cracking process in metastable state controlling, a device is used for the feedstock temperature change in time given mode controlling with the exit into the metastable states temperature range, functionally connected to the consisting of two units heating unit, preheating unit and the rapid heating unit, at that the preheating unit provides the feedstock heating to the temperature below the feedstock boiling point beginning, but not exceeding its thermal stability temperature, and in the rapid heating unit the feedstock is heated to the metastable state predetermined temperature.;EFFECT: enabling the possibility of increase in the thermal cracking processes efficiency and speed.;10 cl, 7 dwg, 1 tbl, 3 ex
机译:技术领域本发明涉及炼油和石化工业,并且可以特别地用于增加重油原料的加工深度。重石油产品热裂解方法包括将高分子量原料进料到加热区,将原料加热到亚临界温度,进行受控的密集热裂解过程,分离轻质馏分,将其余部分进料并与导向加热区,其中裂化是在原料亚稳态下进行的,此时,通过在低压下加热将原料转移到亚稳态,从而能够实现高裂解速率温度T m = 500–790° C,并在此状态下保持一段时间τ m ,此时T m 的值应低于最大过热温度T p < / Sub>,则根据以下条件设定T m / T p 的比率,即亚稳态τ g 的寿命大于破裂时间τ k ,由温度变化模式T的原料按时间τ控制,由给定n函数T = f(τ),分两个阶段进行加热,即预热和快速加热,在此阶段中,第一阶段温度从初始值T 0 升高到温度T 1 ,该温度在开始时低于原料沸点,但未超过其热稳定温度(350-360°C),在第二阶段,原料在0.5至200的时间内迅速过热至亚稳态在给定状态下,液体介质寿命值的5倍,并观察τ g m k 条件。稠油产品热裂解装置包括到加热区供料系统的原料,用于将原料加热到所需温度并确保其热裂解的原料,裂解过程控制装置,剩余部分返回以与原料流混合的装置,其中对于亚稳态控制中的裂化过程,采用一种装置,用于在给定模式控制下,随着进入亚稳态温度范围的出口而及时控制原料温度变化,该装置功能性地连接到由两个单元,预热单元和快速单元组成。加热单元,其中预热单元将原料加热到开始时低于原料沸点的温度,但不超过其热稳定温度,并且在快速加热单元中,原料被加热到亚稳态预定温度。可以提高热裂解过程的效率nd速度;; 10 cl,7 dwg,1 tbl,3 ex

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