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Binuclear coordination compound of europium(III) with mixed ligands, which has luminescent properties

机译:mixed与混合配体的双核配位化合物,具有发光特性

摘要

The invention relates to a binuclear coordination compound of europium(III) with mixed ligands, which has luminescent properties and can be used in optoelectronics.According to the invention, a binuclear coordination compound of europium(III) with the formula [Eu(µ-OC2H5)(btfa)(NO3)(phen)]2·phen is claimed, where btfa is the monoanion of benzoyltrifluoroacetone and phen - 1,10-phenanthroline. The compound is a binuclear complex of europium(III) with three different bidentate ligands. To each europium(III) ion is coordinated one monoanion of benzoyltrifluoroacetone, one molecule of 1,10-phenanthroline and one nitrate anion, and two ethoxy groups, in the role of bridge ligands, connect metal ions to each other. The binuclear compound molecule further comprises one crystallization molecule of 1,10-phenanthroline.The coordination compound has luminescent properties with a maximum photoluminescence at 612 nm.
机译:mixed(Ⅲ)与混合配体的双核配位化合物,具有发光性能,可用于光电子学领域。本发明涉及euro(Ⅲ)的双核配位化合物,其通式为[Eu(μ-要求保护OC2H5)(btfa)(NO3)(phen)] 2·phen,其中btfa是苯甲酰基三氟丙酮和phen-1,10-菲咯啉的单阴离子。该化合物是with(III)与三种不同的双齿配体的双核络合物。在每个euro(III)离子上配位有一个苯甲酰基三氟丙酮单阴离子,一个1,10-菲咯啉分子和一个硝酸根阴离子,以及两个乙氧基基团,它们在桥配体的作用下将金属离子相互连接。双核化合物分子还包含1,10-菲咯啉的一个结晶分子。配位化合物具有发光特性,在612 nm处具有最大的光致发光。

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