New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, applications of complex compounds of europium (III), new luminescent molecular probes for monitoring polymerization processes, new luminescent molecular sensors for tests of coating materials

摘要

the application relates to new systems fotoinicjujących to fotoinicjowanej cation polymerization processes, rodnikowej tiol - en and hybrid new complex compounds europu (iii)methods of manufacturing uses complex compounds europu (iii)new luminescencyjnych molecular probes to monitor polymerization processes and new materials research luminescencyjnych molecular sensor for coating.new systems fotoinicjujące to fotoinicjowanej cation polymerization processes, rodnikowej, tiol - en and hybrid containing salts oniowe and ko - initiator, characterized by that,that contain at least one salt selected from among the following: oniową jodoniowe salts selected from heksafluorofosforanu difenylojodoniowego, heksafluoroantymonianu difenylojodoniowego,heksafluorofosforanu 4 - methyl - 4 '- izopropylodifenylojodoniowego, heksafluorofosforanu 4,4' - dimetylodifenylojodoniowego,tetrakis pentafluorofenyloboranu 4 - methyl - 4 '- izopropylodifenylojodoniowego; salts sulfoniowe selected from heksafluorofosforanu trifenylo - sulfoniowego and heksafluoroantymonianu trifenylosulfoniowego;and at least one ko - initiator selected from the group europu (iii) complex compounds of general formula (1), in which r1 is a substituent selected from among the following: group fenylowa,group 4 - fluorofenylowa, group 4 - metylofenylowa, group 4 - cyjanofenylowa, group 2 - tienylowa, group 2 - furylowa; r2 is selected from among the following: butyl substituent group, group oktylowa,fenylowa group.