Hexamethyldisilazane in the presence of N,N ',N '',N '''-tetramethyltetra-2,3-pyridinoporphyrazinato copper(II) is a new, mild and highly efficient reagent for silylation of alcohols and phenols

Akhlaghinia B; Asadi M; Safaee E; Heydarpoor M

首页> 外文期刊>Phosphorus, Sulfur, and Silicon and the Related Elements >Hexamethyldisilazane in the presence of N,N ',N '',N '''-tetramethyltetra-2,3-pyridinoporphyrazinato copper(II) is a new, mild and highly efficient reagent for silylation of alcohols and phenols

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Hexamethyldisilazane in the presence of N,N ',N '',N '''-tetramethyltetra-2,3-pyridinoporphyrazinato copper(II) is a new, mild and highly efficient reagent for silylation of alcohols and phenols

机译：在N，N'，N''，N'''-四甲基四-2,3-吡啶基卟啉锌铜（II）存在下的六甲基二硅氮烷是一种新型，温和且高效的硅烷化醇和酚的试剂

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Alcohols and phenols are protected with hexamethyldisilazane in the presence of N,N',N",N'''-tetramethyletra-2,3-pyridinoporphyrazinato copper (II) in good-to-excellent yields at room temperature.

机译：在N，N'，N“，N'''-四甲基etra-2,3-吡啶基卟啉锌存在下，用六甲基二硅氮烷在室温下以良好或优异的收率保护六醇。

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《Phosphorus, Sulfur, and Silicon and the Related Elements》 |2004年第10期|共6页
作者
Akhlaghinia B; Asadi M; Safaee E; Heydarpoor M;
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正文语种 eng
中图分类非金属元素及其化合物;
关键词
alcohols; hexamethyldisilazane (HMDS); N; N '; N ''; N '''; tetramethyltetra-2; 3-pyridinoporphyrazinato copper (II); phenols; silylation; TRIMETHYLSILYL ETHERS; CATALYSTS;

机译：醇;六甲基二硅氮烷（HMDS）;N;N';N'';N''';四甲基四-2;3-吡啶并卟啉叠氮铜（II）;酚;硅烷化;三甲基甲硅烷基醚;催化剂;

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1. Hexamethyldisilazane in the presence of N,N ',N '',N '''-tetramethyltetra-2,3-pyridinoporphyrazinato copper(II) is a new, mild and highly efficient reagent for silylation of alcohols and phenols [J] . Akhlaghinia B, Asadi M, Safaee E, Phosphorus, Sulfur, and Silicon and the Related Elements . 2004,第10期

机译：在N，N'，N''，N'''-四甲基四-2,3-吡啶基卟啉锌铜（II）存在下的六甲基二硅氮烷是一种新型，温和且高效的硅烷化醇和酚的试剂
2. Highly regio- and chemoselective silylation of diethyl a-hydroxyphosphonates, alcohols and phenols in the presence of solid TiCl3(OTf) as a catalyst with hexamethyldisilazane (HMDS) at room temperature in the absence of solvent [J] . Habib Firouzabadi, Nasser Iranpoor, Soghra Farahi Catalysis Communications . 2009,第11期

机译：在固态TiCl3（OTf）作为催化剂的情况下，六甲基二硅氮烷（HMDS）在室温下，在不存在溶剂的情况下，对二乙基α-羟基膦酸酯，醇和酚的高度区域选择性和化学选择性甲硅烷基化
3. A mild and efficient method for chemoselective silylation of alcohols using hexamethyldisilazane in the presence of silica chloride [J] . Shirini F., Zolfigol MA., Mohammadi K. Phosphorus, Sulfur, and Silicon and the Related Elements . 2003,第7期

机译：在氯化硅存在下使用六甲基二硅氮烷进行醇化学选择性甲硅烷基化的温和有效方法
4. Highly Efficient Synthesis of Allenyltitanium Reagents Propargyl Alcohol Derivatives.Practical Synthesis of Homopargyl Alcohols [C] . Fang-Long Yang International symposium for Chinese organic chemists . 2000

机译：高效合成亚甲硝基试剂炔丙醇衍生物。常卤醇的实际合成
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6. A Switch between Antioxidant and Prooxidant Properties of the Phenolic Compounds Myricetin Morin 3′4′-Dihydroxyflavone Taxifolin and 4-Hydroxy-Coumarin in the Presence of Copper(II) Ions: A Spectroscopic Absorption Titration and DNA Damage Study [O] . Klaudia Jomová, Lenka Hudecova, Peter Lauro, 2019

机译：铜离子存在下酚类化合物杨梅素桑色素34-二羟基黄酮紫杉醇和4-羟基香豆素的抗氧化剂和促氧化剂性质之间的转换：光谱吸收滴定和DNA损伤研究
7. Rapid and highly efficient trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) catalysed by in situ generated I 2 using Oxone®/KI or cerium ammonium nitrate (CAN)/KI systems under mild conditions [O] . Eskandar Kolvari, Ardeshir Khazaei, Mohammad Ali Zolfigol, 2011

机译：通过在温和条件下使用Oxone®/ ki或硝酸铈/ ki系统在原位生成的I 2催化醇和酚的醇和酚用六甲基二硅氮烷（HMDS）的快速和高效的三甲基甲硅烷基化。

Hexamethyldisilazane in the presence of N,N ',N '',N '''-tetramethyltetra-2,3-pyridinoporphyrazinato copper(II) is a new, mild and highly efficient reagent for silylation of alcohols and phenols

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