Electromagnetic properties of polyaniline/maghemite nanocomposites I. The effect of re-doping time on the electromagnetic properties

摘要

This article is to carry out researches on the synthesis of the polyaniline/gamma-Fe_2O_3 nanocomposites by a reverse micelle process and the effects of re-doping time on the electromagnetic properties of polyaniline/gamma-Fe_2O_3 nanocomposites, investigated by Fourier transform spectrometer (FT-IR), X-ray photoelectron spectroscopy (XPS), wide angle X-ray diffraction diffractometer (WAXD), impedance analyzer, micro-ohmeter, and superconductor quantum interference device (SQUID). The nanostructure of the polyaniline/gamma-Fe_2O_3 nanocomposites was characterized by micrographs of transmission electron microscopy (TEM). It was found that the dispersed gamma-Fe_2O_3 phase is roughly distributed in the polyaniline matrix. Results showed that, in the presence of gamma-Fe_2O_3, the growth rate of quinoid ring is markedly retarded. The crystallinity and doping level of polyaniline in the nanocomposites increase with re-doping time, the conductivity and dielectric properties (i.e., permittivity and loss factor) of nanocomposites are hence increased and the ionic polarization relaxation time become shorter from 1.71 X 10~(-9) to 7.48 X 10~(-10) s. The particle size and gamma-Fe_2O_3 content in the nanocomposites decrease with re-doping time due to the reduction effect resulting from the doped protonic acid of polyaniline. For the room-temperature SQUID analysis, the superparamagnetic behavior is observed, suggesting the presence of the thermal activation energy contribution to the magnetic moment. The saturated magnetization was decreased with decreasing gamma-Fe_2O_3 contents.