A vibrational spectroscopic study of a hydrated hydroxy-phosphate mineral fluellite, Al_2(PO_4)F_2(OH)·7H_2O

Ji?í ?ejka; Ji?í Sejkora; Ivo Macek; Ray L. Frost; Andrés López; Ricardo Scholz; Yunfei Xi

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A vibrational spectroscopic study of a hydrated hydroxy-phosphate mineral fluellite, Al_2(PO_4)F_2(OH)·7H_2O

机译：水合羟基磷酸盐矿物纤锌矿Al_2（PO_4）F_2（OH）·7H_2O的振动光谱研究

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摘要

Raman and infrared spectra of two well-defined fluellite samples, Al_2(PO_4)F_2(OH)·7H_2O, from the Krásno near Horní Slavkov (Czech Republic) and Kapunda, South Australia (Australia) were studied and tentatively interpreted. Observed bands were assigned to the stretching and bending vibrations of phosphate tetrahedra, aluminum oxide/hydroxide/fluoride octahedra, water molecules and hydroxyl ions. Approximate O-H…O hydrogen bond lengths were inferred from the Raman and infrared spectra.

机译：研究并初步解释了来自霍尼斯拉夫科夫（捷克共和国）和南澳大利亚Kapunda附近的Krásno的两个定义明确的萤石样品Al_2（PO_4）F_2（OH）·7H_2O的拉曼光谱和红外光谱。观察到的谱带分配给磷酸盐四面体，氧化铝/氢氧化物/氟化物八面体，水分子和氢氧根离子的拉伸和弯曲振动。从拉曼光谱和红外光谱推断出近似的O-H…O氢键长度。

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《Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy》 |2014年第null期|共7页
作者
Ji?í ?ejka; Ji?í Sejkora; Ivo Macek; Ray L. Frost; Andrés López; Ricardo Scholz; Yunfei Xi;
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正文语种 eng
中图分类光化学分析法（光谱分析法）;
关键词
Fluellite; Phosphate; Hydroxyl ions; Raman spectroscopy; Infrared spectroscopy;

机译：萤石;磷酸盐;羟基离子;拉曼光谱;红外光谱;

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1. A vibrational spectroscopic study of a hydrated hydroxy-phosphate mineral fluellite, Al_2(PO_4)F_2(OH)·7H_2O [J] . Ji?í ?ejka, Ji?í Sejkora, Ivo Macek, Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2014,第Null期

机译：水合羟基磷酸盐矿物纤锌矿Al_2（PO_4）F_2（OH）·7H_2O的振动光谱研究
2. Raman spectroscopic study of the hydroxy-phosphate mineral plumbogummite PbAl_3(PO_4)_2(OH,H_2O)_6 [J] . Frost R.L., Palmer S.J., Xi Y., Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2013,第Null期

机译：羟基磷酸盐矿物铅锌矿PbAl_3（PO_4）_2（OH，H_2O）_6的拉曼光谱研究
3. The phosphate mineral sigloite Fe~(3+)Al_2(PO _4)_2(OH)_3·7(H_2O), an exception to the paragenesis rule - A vibrational spectroscopic study [J] . Frost R.L., Xi Y., Scholz R., Journal of Molecular Structure . 2013,第Null期

机译：共生准则的一个例外-磷酸盐矿物硅铁矿Fe〜（3+）Al_2（PO _4）_2（OH）_3·7（H_2O）-振动光谱研究
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7. A vibrational spectroscopic study of a hydrated hydroxy-phosphate mineral fluellite, Al2(PO4)F2(OH)·7H2O [O] . Cejka Jiri, Sejkora Jiří, Macek Ivo, 2014

机译：水合羟基磷酸盐矿物纤锌矿Al2（PO4）F2（OH）·7H2O的振动光谱研究

A vibrational spectroscopic study of a hydrated hydroxy-phosphate mineral fluellite, Al_2(PO_4)F_2(OH)·7H_2O

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