Cyano-Bridged Complexes Based on Re Tetrahedral Cluster Anions,Ni2+ Cations,and Poly dentate Amines

摘要

Interaction of the tetrahedral chalcocyanide cluster anionic complexes of Re,K4[Re4Q4(CN)12](Q = S,Se,Te),with Ni2+ cationic complexes with polydentate amines,such as ethylenediamine(En),diefhyl-enetriamine(Dien),or triethylenetetraamine(Trien)was used to synthesize six novel complexes:[Ni(NH3)4(En)][{Ni(NH3)(En)2}Re4Te4(CN)12]·2H2O,[{Ni(En)2}2Re4Se4(CN)12]·3.5H2O,[Ni(NH3)3(Dien)]2[Re4Se4(CN)12]·5.5H2O,[{Ni(NH3)2(Dien)}2Re4Te4(CN)12]·2.5H2O,rNi(NH3)2(Trien)][{Ni(NH3)(Trien)}Re4Se4(CN)12]·2.5H2O,[{Ni(Trien)}2Re4S4(CN)12]·3H2O.The complexes were studied by single-crystal X-ray diffraction analysis.