Organosilicon Amidophosphates and Their Eu and Er Complexes in Solutions and Films:Spectral and Luminescence Properties

摘要

Fluorescence and fluorescence excitation spectra of phosphorus-containing organosilicon ligands O=PX_2NHR (X=NMe_2,OPh;R=CH_2CH_2CH_2Si(OEt)_3 and their Eu(IH) complexes in acetonitrile solutions and in films are studied.In UV region (285-420 nm),bis(dimethylamido)triethoxysilylpropylamidophosphate (X=NMe_2) and diphenyltriethoxysilylpropylamidophosphate (X=OPh) exhibit two emission bands,whose position and intensity depend on the nature of substituents at the phosphorus atom.The Eu complexes show the ligand and the cation luminescence.The emission bands of coordinated ligands are shifted to long-wave region.The cation luminescence appears as three or four bands due to f-f transitions from the excited ~5D_0 level to the lower ~7F_(1-4) levels.The most intense transition is ~5D_0 -> ~7F_2.The emission band in a region of 420 nm appears in solutions and films prepared from both pure ligands and their Eu(III) complexes.This band is due to luminescence of spatially crosslinked nanoparticles of sesquioxane structure.The intensity ratio of the Eu~(3+) emission bands changes when going from solutions to films,the emission intensity increases in a range of 420 nm.Films containing incorporated Er complexes with amidophosphates show intense luminescence of a matrix at 430 nm and a series of weak narrow bands due to the Er~(3+) cation at 550-700 nm.