Relationship Between Thermodynamical Parameters of Activated Complexes and Initial Reactants in the Reaction of Peroxides with Amines

摘要

A linear dependence between heats of formation and entropies of initial reactants, on the one hand, and the corresponding thermodynamical parameters of activated complexes, on the other hand, was obtained for the reaction of peroxides with amines. The relationship allows to estimate these parameters for another similar reactions of amines with peroxides.