Synthesis of Unsymmetrical Diarylmethanes by Cross-Coupling between Aryl Triflates and Tetrabutylammonium Difluorotribenzylstannate

Antonio Garcia Martinez; Jose Osio Barcina; Maria del Rosario Colorado Heras; Alvaro de Fresno Cerezo

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Synthesis of Unsymmetrical Diarylmethanes by Cross-Coupling between Aryl Triflates and Tetrabutylammonium Difluorotribenzylstannate

机译：通过芳基三氟甲磺酸酯与四丁基铵二氟三苄基锡酸酯的交叉偶联合成不对称二芳基甲烷

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The benzylation of aryl triflates can be achieved by cross-coupling between aryl triflates and the new hypervalent tin reagent (n-Bu_4N)~+(Bn_3SnF_2)~-.

机译：芳基三氟甲磺酸酯的苄基化可通过芳基三氟甲磺酸酯与新的高价锡试剂（n-Bu_4N）〜+（Bn_3SnF_2）〜-之间的交叉偶联来实现。

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《Organic letters》 |2000年第10期|共2页
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Antonio Garcia Martinez; Jose Osio Barcina; Maria del Rosario Colorado Heras; Alvaro de Fresno Cerezo;
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正文语种 eng
中图分类有机化学;
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1. Synthesis of Unsymmetrical Diarylmethanes by Cross-Coupling between Aryl Triflates and Tetrabutylammonium Difluorotribenzylstannate [J] . Antonio Garcia Martinez, Jose Osio Barcina, Maria del Rosario Colorado Heras, Organic letters . 2000,第10期

机译：通过芳基三氟甲磺酸酯与四丁基铵二氟三苄基锡酸酯的交叉偶联合成不对称二芳基甲烷
2. Efficient synthesis of diarylmethane derivatives by PdCl2 catalyzed cross-coupling reactions of benzyl chlorides with aryl boronic acids in aqueous medium [J] . Zhao Guangkuan, Zhang Kena, Wang Liang, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2015,第48期

机译：在水性介质中，PdCl2催化苄基氯与芳基硼酸的交叉偶联反应有效合成二芳基甲烷衍生物
3. Cross-couplings between benzylic and aryl halides 'on water': synthesis of diarylmethanes [J] . Christophe Duplais, Arkady Krasovskiy, Alina Wattenberg, Chemical Communications . 2010,第4期

机译：苄基卤化物与芳基卤化物“在水上”的交叉偶联：二芳基甲烷的合成
4. Synthesis of Aryl Phosphines by Palladium Catalyzed Phosphination of Aryl bromides and triflates with Triarylphosphines [C] . Fuk Yee Kwong International symposium for Chinese organic chemists . 2000

机译：钯芳溴化钯催化合成芳基膦酸磷酸酯和三芳基膦酸酯
5. Methodological and comparative studies on directed ortho metallation of aryl tert-butyl sulfoxides and Ni(0)-catalyzed cross-coupling of aryl triflates and O-aryl carbamates. Studies directed toward the total synthesis of sterigmatocystin. [D] . Quesnelle, Claupe A. 1996

机译：方法学和比较研究的芳基叔丁基亚砜的定向原位金属化和芳基三氟甲磺酸酯和O-芳基氨基甲酸酯的Ni（0）催化的交叉偶联。研究针对全囊藻毒素的合成。
6. Correction to Palladium-catalyzed Cross-Coupling of Aryl Chlorides and Triflates with Sodium Cyanate: A Practical Synthesis of Unsymmetrical Ureas [O] . Ekaterina V. Vinogradova, Brett P. Fors, Stephen L. Buchwald -1

机译：对钯催化的芳基氯化物和三氟甲磺酸与氰酸盐的交叉偶联的偶联反应：不对称尿素的实用合成
7. Palladium-Catalyzed Cross-Coupling of Aryl Chlorides and Triflates with Sodium Cyanate: A Practical Synthesis of Unsymmetrical Ureas [O] . Fors, Brett P., Vinogradova, Ekaterina Viktor, Buchwald, Stephen Leffler 2012

机译：钯催化的氯化铝和三氟甲磺酸酯与氰酸钠的交叉偶联：非对称脲的实际合成

Synthesis of Unsymmetrical Diarylmethanes by Cross-Coupling between Aryl Triflates and Tetrabutylammonium Difluorotribenzylstannate

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