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Clausius' entropy revisited

机译:克劳修斯的熵再探

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摘要

Conventional nonequilibrium thermodynamics is mainly concerned with systems in local equilibrium and their entropy production, due to the irreversible processes which take place in these systems. In this paper, fluids will be considered in a state of local equilibrium. We argue that the main feature of such systems is not the entropy production, but the organization of the flowing currents in such systems. These currents do not only have entropy production, but must also have an organization needed to flow in a certain direction. It is the latter, which is the source of the equilibrium entropy, when the fluid goes from a local equilibrium state to an equilibrium state. This implies a transmutation of the local equilibrium currents' organization into the equilibrium entropy. Alternatively, when a fluid goes from an equilibrium state to a local equilibrium state, its entropy transmutes into the organization of the currents of that state.
机译:常规的非平衡热力学主要涉及局部平衡​​中的系统及其熵的产生,这是由于在这些系统中发生的不可逆过程。在本文中,流体将被视为处于局部平衡状态。我们认为,此类系统的主要特征不是熵产生,而是此类系统中流动电流的组织。这些电流不仅产生熵,而且还必须具有沿特定方向流动所需的组织。当流体从局部平衡状态变为平衡状态时,后者就是平衡熵的来源。这意味着将局部平衡电流的组织转变为平衡熵。可替代地,当流体从平衡状态变为局部平衡状态时,其熵转化为该状态的电流的组织。

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