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Development and characterization of an amperometric sensor for triclosan detection based on electropolymerized molecularly imprinted polymer

机译:基于电聚合分子印迹聚合物的三氯生安培传感器的开发与表征

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摘要

A novel amperometric sensor based on electropolymerized molecularly imprinted polymer (MIP) for triclosan detection is reported. The sensor was prepared by electropolymerizing o-phenylenediamine (o-PD) on a glassy carbon electrode in the presence of template triclosan. The template can be quickly removed by NaOH solution. After incubating in acetate buffer for 15 min, the sensor response sensitively to triclosan over a linear range of 2.0 x 10(-7) to 3.0 x 10(-6) mol/L and a detection limit as low as 8.0 x 10(-8) mol/L is obtained. This sensor provides an efficient way for eliminating interferences from compounds with similar structures to that of triclosan.
机译:报道了一种基于电聚合分子印迹聚合物(MIP)的新型安培传感器,用于三氯生检测。通过在模板三氯生存在下在玻璃碳电极上电聚合邻苯二胺(o-PD)来制备传感器。可以用NaOH溶液快速除去模板。在醋酸盐缓冲液中孵育15分钟后,传感器对三氯生的响应在2.0 x 10(-7)到3.0 x 10(-6)mol / L的线性范围内敏感,检测限低至8.0 x 10(-) 8)获得摩尔/升。该传感器为消除与三氯生具有相似结构的化合物产生的干扰提供了有效的方法。

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