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Performance of Cotton Fabric Treated with an Amino-terminated Hyperbranched Polymer

机译:氨基末端超支化聚合物处理棉织物的性能

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摘要

An amino-terminated hyperbranched polymer (HBP-NH2), synthesized from methyl acrylate and diethylene tri-amine by polycondensation, was applied to treat cotton samples by a pad-dry-cure method. Physical properties, salt-free dye-ability, antimicrobial activity, and antiultraviolet property of the treated cotton samples were tested. The crystallinity and mechanical properties, including breaking strength, breaking elongation, and Young's modulus of the treated cotton fibers, increased slightly in comparison with those of the untreated cotton fibers. The thermal stability and the moisture regain were also improved slightly. Dyed with direct dyes and reactive dyes in the absence of the electrolytes, the treated cotton fabric showed similar or higher color strength compared with the untreated cotton fabric in conventional dyeing. The treated cotton fabric can also be dyed with acid dyes effectively. In addition, the treated cotton fabric showed good antimicrobial activities against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli). The study of the antiultraviolet properties of the treated cotton fabric indicated that the HBP-NH2 contributed to the reduction of UV transmission and the increase of UPF.
机译:由丙烯酸甲酯和二亚乙基三胺经缩聚反应制得的氨基端基超支化聚合物(HBP-NH2),通过垫干固化法应用于棉花样品。测试了处理过的棉样品的物理性能,无盐染色能力,抗菌活性和抗紫外线性能。与未处理的棉纤维相比,处理过的棉纤维的结晶度和机械性能,包括断裂强度,断裂伸长率和杨氏模量,略有提高。热稳定性和回潮率也略有提高。在没有电解质的情况下用直接染料和活性染料染色,与常规染色中未处理的棉织物相比,处理后的棉织物显示出相似或更高的色强度。处理过的棉织物也可以有效地用酸性染料染色。另外,处理过的棉织物对金黄色葡萄球菌(S.aureus)和大肠杆菌(E.coli)显示出良好的抗菌活性。对处理过的棉织物的抗紫外线性能的研究表明,HBP-NH2有助于减少紫外线透过和增加UPF。

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