Synthesis and Molecular Structure of Novel Cyclic Organohydroborate Hafnocene Complex (eta~5-C_5H_5)_2Hf{(mu-H)_2BC_8H_(14)}_2

摘要

There has been an effort with respect to the investigation of the interaction of boranes with organotransition metal compounds,especially in regard to their role in transition metal catalyzed hydroboration and various B-C bond formation reactions.Although a number of metallahydro-borate complexes have been studied,hydroborate derivatives of metallocenes,especially organohydroborate derivatives have received significantly less attention.