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Cadmium Biosorption from Aqueous Solutions by Fucus Vesiculosus L.: Sorption Mechanisms

机译:悬钩子从水溶液中对镉的生物吸附:吸附机理

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摘要

Cadmium is present in different types of industrial effluents, and responsible for environmental pollution. Biosorption of heavy metals can be an effective process for the removal and recovery of heavy metal ions from aqueous solutions. The biomass ofmarine algae has been reported to have high uptake capacities for a number of heavy metal ions. In this paper, the adsorption properties of a pre-treated biomass of marine algae Fucus vesiculosus for Cd (II) were investigated. Equilibrium isotherms andkinetic studies were carried out for the biosorption of Cd (II) ions from aqueous solutions using the algae brown biomass from batch adsorption experiments. The equilibrium time was about 300 min and the adsorption equilibrium data were well described byLangmuir's equation. It was found that the Langmuir isotherm fitted the experimental data better than the Freundlich isotherm. The characterization of the surface functional groups was performed with this method, a qualitative analysis with the study ofFT-IR spectrum, using the single extrapolation method. The maximum adsorption capacity has been extrapolated to 0.85 mmol/g~(-1).
机译:镉存在于不同类型的工业废水中,对环境造成污染。重金属的生物吸附可能是从水溶液中去除和回收重金属离子的有效方法。据报道,海藻的生物量对多种重金属离子具有高吸收能力。本文研究了一种预处理过的海藻褐藻(Fusus vesiculosus)生物量对Cd(II)的吸附特性。使用分批吸附实验中的藻褐生物质对水溶液中Cd(II)离子的生物吸附进行了平衡等温线和动力学研究。平衡时间约为300分钟,Langmuir方程很好地描述了吸附平衡数据。发现Langmuir等温线比Freundlich等温线更适合实验数据。用这种方法进行表面官能团的表征,并使用单外推法对FT-IR光谱进行定性分析。最大吸附容量已推断为0.85 mmol / g〜(-1)。

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