Synthesis and structural characterization of ruthenium nitrosonaphthol complexes incorporating pendant pyridyl lijgands

摘要

Ruthenium nitrosonaphthol complexes incorporating pendant pyridyl ligands of trans- and cis-[Ru{#eta#~2-N(O)C_10H_6O}_2(CO)(NC_5H_4JCHCHC_5H_4N)] (1a and 1b) and trans- and cis-[Ru{#eta#~2-OC_10H_6N(O)}_2(CO)(NC_5H_4CHCHC_5H_4N)] (1c and 1d) were synthesized and used as building blocks in the construction of a supramolecular system. The molecular structures of 1b and the NMe_3 substitution complex cis-[Ru{#eta#_2-N(O)C_10H_6O}_2(CO)(NMeDd_3)] (2b) were established by X-ray diffraction analysis.