An unusual cis-phosphonodithioato Pd(II) complex in an extensive hydrogen bonding 3D network

摘要

The P-N bond hydrolysis of the 4-methoxyphenyl-ammoniumethylamido-phosphonodithioato ligand on complexation to Pd-11 leads to the first example of a Pd-phosphonodithioato complex in a cis configuration, stabilised in the solid state by an extended network of hydrogen bondings involving the released ethylenediamine and a water molecule. (C) 2004 Elsevier B.V. All rights reserved.