The effect of different heterogeneous and homogeneous photocatalytic systems on the oxidative degradation of mepiquat chloride in aqueous solutions was investigated. In the case of heterogeneous reactions, the influence of five factors was studied: the type of catalyst, photocatalyst concentration, pH, pesticide concentration, and the presence of H_2O_2 and/or Fe~(3+). For homogeneous catalysis, other factors were studied: the oxidising agent and the light source. Nearly complete degradation of mepiquat chloride was obtained after about 180 minutes in the presence of an acid medium (pH3) using a UV-A lamp and TiO_2P-25 catalyst (0.5 g/L), for an initial pesticide concentration of 10 ppm. Degradation rates corresponding to homogeneous photocatalysis were lower compared to those corresponding to the use of TiO_2 as the photocatalyst.
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机译:研究了不同的均相和均相光催化体系对盐酸异丙基哌嗪在水溶液中的氧化降解的影响。在非均相反应的情况下,研究了五个因素的影响:催化剂的类型,光催化剂的浓度,pH,农药的浓度以及H_2O_2和/或Fe〜(3+)的存在。对于均相催化,还研究了其他因素:氧化剂和光源。在酸性介质(pH3)存在下,使用UV-A灯和TiO_2P-25催化剂(0.5 g / L)在约180分钟后,对于农药的初始浓度为10 ppm,甲哌喹氯化物几乎完全降解。与使用TiO_2作为光催化剂的降解速率相比,均相光催化的降解速率更低。
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