A two-dimensional Cd(II) coordination polymer:[Cd(l,4-BDOA)(l,10-phen)] centre dot H_2O with strong blue fluorescent emission constructed by benzene-1,4-dioxydiacetate ligand

摘要

Hydrothermal reaction of Cd(NO_3)_2 centre dot 4H_2O with 1,10-phen and 1,4-BDOAH_2 yields a two-dimensional cadmium(II) coordination polymer,[Cd(l,4-BDOA)(1,10-phen)] centre dot H_2O,in which CdN_2O_5 pentagonal bipyramids are linked together to construct a lamellar structure.It exhibits strong blue fluorescent upon photoexcitation.