Formal total synthesis of 2-pupukeanone via radical mediated cyclisation of an enyne

A Srikrishna; D Vijaykumar; G V R Sharma

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Formal total synthesis of 2-pupukeanone via radical mediated cyclisation of an enyne

机译：通过自由基介导的烯炔的环化反应，正式合成2-pupukeanone

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Diels-Alder reaction of the dienone 12,obtained by C-alkylation of sodium 2,6-dimethylphenoxide,with acrylonitrile and phenyl vinyl sulfones generate the enynes 14 and 17.

机译：通过2，6-二甲基苯氧基钠的C-烷基化获得的二烯酮12与丙烯腈和苯基乙烯基砜的Diels-Alder反应生成烯炔14和17。

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《Indian Journal of Chemistry, Section B. Organic Including Medicinal》 |1999年第7期|共5页
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A Srikrishna; D Vijaykumar; G V R Sharma;
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中图分类化学;化学工业;
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1. Formal total synthesis of 2-pupukeanone via radical mediated cyclisation of an enyne [J] . A Srikrishna, D Vijaykumar, G V R Sharma Indian Journal of Chemistry, Section B. Organic Including Medicinal . 1999,第7期

机译：通过自由基介导的烯炔的环化反应，正式合成2-pupukeanone
2. SmI2-Mediated Radical Coupling Strategy to Securinega Alkaloids: Total Synthesis of (-)-14,15-Dihydrosecurinine and Formal Total Synthesis of (-)-Securinine [J] . Zheng Xiao, Liu Juan, Ye Chen-Xi, The Journal of Organic Chemistry . 2015,第2期

机译：SmI 2介导的Securinega生物碱的自由基偶联策略：（-）-14,15-Dihydrosecurinine的全合成和（-）-Securinine的形式全合成
3. Stereoselective synthesis of trans-THF rings using an oxidative cyclisation-radical deoxygenation sequence: application to the formal synthesis of trans-(2R,5R)-linalool oxide [J] . Sheikh Nadeem S. RSC Advances . 2015,第6期

机译：使用氧化环化-自由基脱氧序列的立体选择性合成反式-THF环：在反式-（2R，5R）-芳樟醇氧化物的正式合成中的应用
4. SYNTHESIS OF GLYCOSIDASE INHIBITORS VIA FREE RADICAL CYCLISATION REACTIONS: NEW SYNTHETIC APPROACHES TO IMINOSUGARS AND THIOSUGARS [C] . Malone. A. M., Scanlan E. M. International Carbohydrate Symposium . 2013

机译：通过自由基环化反应合成糖苷酶抑制剂：新的伊纳尼亚州和硫代硫代斯的新合成方法
5. Part one: Generation and cyclization of nitrogen radicals. Application to a formal total synthesis of (+/-)-peduncularine. Part two: Studies towards the total synthesis of chartelline A. [D] . Lin, Xichen. 2002

机译：第一部分：氮自由基的产生和环化。适用于（+/-）-peduncularine的正式全合成。第二部分：关于沙特琳娜A总合成的研究。
6. A racemic formal total synthesis of clavukerin A using gold(I)-catalyzed cycloisomerization of 3-methoxy-16-enynes as the key strategy [O] . Jae Youp Cheong, Young Ho Rhee 2011

机译：以金（I）催化的3-甲氧基-16-烯炔的环异构化为外消旋形式的克拉维酮A的全合成
7. A racemic formal total synthesis of clavukerin A using gold(I)-catalyzed cycloisomerization of 3-methoxy-1,6-enynes as the key strategy [O] . Cheong, Jae Youp, Rhee, Young Ho 2011

机译：以金（I）催化的3-甲氧基-1,6-烯炔的环异构化为外消旋形式的克拉维酮A的全合成

Formal total synthesis of 2-pupukeanone via radical mediated cyclisation of an enyne

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