Cobalt-Iron Oxide Nanoarrays Supported on Carbon Fiber Paper with High Stability for Electrochemical Oxygen Evolution at Large Current Densities

摘要

Here, we demonstrate that nonprecious CoFe-based oxide nanoarrays exhibit excellent electrocatalytic activity and superior stability for electrochemical oxygen evolution reaction (OER) at large current densities (500 mA cm(-2)). Carbon fiber paper (CFP) with three-dimensional macroporous structure, excellent corrosion resistance, and high electrical properties is used as the support material to prevent surface passivation during the long-term process of OER. Through a facile method of hydrothermal synthesis and thermal treatment, vertically aligned arrays of spinel CoxFe3-xO4 nanostructures are homogeneously grown on CFP. The morphology and the Fe-doping content of the CoFe oxide nanoarrays can be controlled by the Fe3+ concentration in the precursor solution. The arrays of CoFe oxide nanosheets (NSs) grown on CFP (Co2.3Fe0.7O4-NSs/CFP) deliver lower Tafel slope (34.3 mV dec(-1)) than CoFe oxide nanowire (NW) arrays grown on CFP (Co2.7Fe0.3O4-NVVs/CFP) in alkaline solution, owing to higher Fe-doping content and larger effective specific surface area. The Co2.3Fe0.7O4-NSs/CFP electrode exhibits excellent stability for OER at large current densities in alkaline solution. Moreover, the morphology and structure of CoFeO nanoarrays are well preserved after long-term testing, indicating the high stability for OER.